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919780

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads

solid

Synonyme(s) :

Pd(dppf)Cl2

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A propos de cet article

Formule linéaire :
(C17H14P)2Fe . PdCl2
Numéro CAS:
72287-26-4
MDL number:
MFCD00015757
UNSPSC Code:
12352103
NACRES:
NA.22
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Nom du produit

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads,

Quality Level

100

product line

ChemBeads

form

solid

composition

~ 4 wt.% loading of catalyst

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

SMILES string

[Pd+2].[Fe+2].P(c6c[c-H]cc6)(c5ccccc5)c4ccccc4.P(c3c[c-H]cc3)(c2ccccc2)c1ccccc1.[Cl-].[Cl-]

InChI

1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q2*-1;;;2*+2/p-2

InChI key

NXQGGXCHGDYOHB-UHFFFAOYSA-L

Application

Catalyst for C-C and C-N coupling reaction.
Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:
  • Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
  • Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
  • Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

For larger scale uses, product also available in powdered form (697230) & (931217)

Other Notes

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

pictograms

Health hazard
GHS08

signalword

Danger

hcodes

H350i

Hazard Classifications

Carc. 1B Inhalation

Classe de stockage

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Consulter la Bibliothèque de documents

Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling reaction of a secondary alkyl grignard reagent with organic halides
Hayashi T, et al.
Tetrahedron Letters, 20(21), 1871-1874 (1979)
Star−Shaped Oligothiophenes for Solution−Processible Organic Field-Effect Transistors
Ponomarenko S A, et al.
Advances in Functional Materials, 13(8), 591-596 (2003)
Sho Fujii et al.
Physical chemistry chemical physics : PCCP, 19(42), 28943-28949 (2017-10-24)
A novel sensor, 4-[2-(9-anthryl)ethynyl]-1,10-phenanthroline (1), exhibits highly intense fluorescent in the wavelength region of 440-600 nm (maximum wavelength (λf) = 470 nm) with the quantum yield (Φf) and lifetime (τf) being 0.90 and 4.2 ns, respectively, in CH3CN at 298
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Numéro d'article de commerce international

RéférenceGTIN
919780-1G04065265473903
919780-250MG04065265473910