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909343

2-(4-Fluorophenyl)-5-methylpyridine

≥95%

Synonyme(s) :

p-F(Me)ppy

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A propos de cet article

Formule empirique (notation de Hill) :
C12H10FN
Numéro CAS:
85237-65-6
Poids moléculaire :
187.21
UNSPSC Code:
12352101
MDL number:
MFCD09037512
Assay:
≥95%
Form:
powder or crystals
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assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

mp

58-59 °C

InChI

1S/C12H10FN/c1-9-2-7-12(14-8-9)10-3-5-11(13)6-4-10/h2-8H,1H3

InChI key

WSVYYUKIXFSDTE-UHFFFAOYSA-N

Application

2-(4-Fluorophenyl)-5-methylpyridine is a ligand used for the preparation of Ir(III) photocatalysts.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Highly Fluorinated Ir(III)−2,2′:6′,2″−Terpyridine-Phenylpyridine−X Complexes via Selective C−F Activation: Robust Photocatalysts for Solar Fuel Generation and Photoredox Catalysis

Classe de stockage

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Jonathan A Porras et al.
Journal of the American Chemical Society, 138(30), 9460-9472 (2016-07-09)
A series of fluorinated Ir(III)-terpyridine-phenylpyridine-X (X = anionic monodentate ligand) complexes were synthesized by selective C-F activation, whereby perfluorinated phenylpyridines were readily complexed. The combination of fluorinated phenylpyridine ligands with an electron-rich tri-tert-butyl terpyridine ligand generates a "push-pull" force on
Yufan Liang et al.
Nature, 559(7712), 83-88 (2018-06-22)
Over the past three decades, considerable progress has been made in the development of methods to construct sp2 carbon-nitrogen (C-N) bonds using palladium, copper or nickel catalysis1,2. However, the incorporation of alkyl substrates to form sp3 C-N bonds remains one
Yong Yao Loh et al.
Science (New York, N.Y.), 358(6367), 1182-1187 (2017-11-11)
Deuterium- and tritium-labeled pharmaceutical compounds are pivotal diagnostic tools in drug discovery research, providing vital information about the biological fate of drugs and drug metabolites. Herein we demonstrate that a photoredox-mediated hydrogen atom transfer protocol can efficiently and selectively install
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