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MilliporeSigma

908576

WinterGreen photocage

≥95%

Synonyme(s) :

(1,3,5,5,7,9-Hexamethyl-dipyrrolo[1,3,2]diazaborinin-10-yl)methanol, 4,4′-Dimethyl-8-hydroxymethyl-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene, BODIPY photocage, Imidazole-protected BODIPY alcohol

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assay

≥95%

form

powder or crystals

storage temp.

2-8°C

Application

Green-light absorbing photocage. Easily functionalized to ester with DCC/EDC couplings for photorelease of carboxylic acids.

Legal Information

US Patent Application #16/140,218


Classe de stockage

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Contenu apparenté

Research in the Winter lab focuses on the development of new chemical tools for biological and medical applications. Philosophically, we take the view that many problems in biology are at heart problems in mechanistic physical organic chemistry


Tomáš Slanina et al.
Journal of the American Chemical Society, 139(42), 15168-15175 (2017-10-19)
A detailed investigation of the photophysical parameters and photochemical reactivity of meso-methyl BODIPY photoremovable protecting groups was accomplished through systematic variation of the leaving group (LG) and core substituents as well as substitutions at boron. Efficiencies of the LG release
Pratik P Goswami et al.
Journal of the American Chemical Society, 137(11), 3783-3786 (2015-03-10)
Photoremovable protecting groups derived from meso-substituted BODIPY dyes release acetic acid with green wavelengths >500 nm. Photorelease is demonstrated in cultured S2 cells. The photocaging structures were identified by our previously proposed strategy of computationally searching for carbocations with low-energy