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904945

[Ru(dmbpy)₃](PF₆)₂

Name: [Ru(dmbpy)3](PF6)2
Brand: ALDRICH

≥95%, powder or crystals

Synonyme(s) :

Tris(4,4′-dimethyl-2,2′-bipyridine)ruthenium bis(hexafluorophosphate)

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A propos de cet article

Formule empirique (notation de Hill) :

C₃₆H₃₆F₁₂N₆P₂Ru

Numéro CAS:

83605-44-1

Poids moléculaire :

943.71

MDL number:

MFCD28369258

UNSPSC Code:

12352101

NACRES:

NA.22

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Propriétés

Nom du produit

[Ru(dmbpy)₃](PF₆)₂, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

SMILES string

[Ru].n5c(cc(cc5)C)c6nccc(c6)C.n3c(cc(cc3)C)c4nccc(c4)C.n1c(cc(cc1)C)c2nccc(c2)C.C

InChI

1S/3C12H12N2.CH4.Ru/c3*1-9-3-5-13-11(7-9)12-8-10(2)4-6-14-12;;/h3*3-8H,1-2H3;1H4;

InChI key

YXZDNATXDNOJQJ-UHFFFAOYSA-N

Description

Application

This ruthenium photocatalyst facilitates a variety of transformations using visible light.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Highly efficient, selective, and durable photocatalytic system for CO₂ reduction to formic acid

Classe de stockage

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Generating carbyne equivalents with photoredox catalysis.

Zhaofeng Wang et al.

Nature, 554(7690), 86-91 (2018-02-02)

Carbon has the unique ability to bind four atoms and form stable tetravalent structures that are prevalent in nature. The lack of one or two valences leads to a set of species-carbocations, carbanions, radicals and carbenes-that is fundamental to our

Highly efficient, selective, and durable photocatalytic system for CO2 reduction to formic acid.

Yusuke Tamaki et al.

Chemical science, 6(12), 7213-7221 (2015-12-01)

We discovered an extremely suitable sacrificial electron donor, 1,3-dimethyl-2-(o-hydroxyphenyl)-2,3-dihydro-1H-benzo[d]imidazole, for the selective photocatalytic reduction of CO2 to formic acid using a Ru(ii)-Ru(ii) supramolecular photocatalyst. The efficiency, durability, and rate of photocatalysis are significantly increased (ΦHCOOH = 0.46, TONHCOOH = 2766