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729345

Hoveyda-Grubbs Catalyst® M722

solid, Umicore

Synonyme(s) :

Grubbs Catalyst® C711, Hoveyda-Grubbs Catalyst® M72 SIPr (C711), Dichloro[1,3-bis(2,6-isopropylphenyl)-2-imidazolidinylidene](2-isopropoxyphenylmethylene)ruthenium(II)

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A propos de cet article

Formule empirique (notation de Hill) :
C37H50Cl2N2ORu
Numéro CAS:
Poids moléculaire :
710.78
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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Nom du produit

Hoveyda-Grubbs Catalyst® M722, Umicore

Quality Level

product line

Grubbs Catalyst® M700 Series

form

solid

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Ring-Opening Polymerization

manufacturer/tradename

Umicore Grubbs Catalyst® M700 Series

mp

242-246 °C

storage temp.

2-8°C

SMILES string

CC(C)Oc1ccccc1C=[Ru](Cl)(Cl)=C2N(CCN2c3c(cccc3C(C)C)C(C)C)c4c(cccc4C(C)C)C(C)C

InChI

1S/C27H38N2.C10H12O.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-8(2)11-10-7-5-4-6-9(10)3;;;/h9-14,18-21H,15-16H2,1-8H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2

InChI key

ONAWWBRGWXRMAF-UHFFFAOYSA-L

Application

Preferred catalyst for making trisubstituted olefins by cross metathesis.

Packaging

100 mg, 500 mg, 2 g in glass bottle.

Legal Information

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG


Classe de stockage

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable



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Contenu apparenté

The Olefin Application Metathesis Application Guide provides - The Key Features of Metathesis, General Reaction Procedures, Guidance for Choosing the Correct Metathesis Route, A Metathesis Quick Guide

Research focuses on ruthenium alkylidene complexes for versatile olefin metatheses catalysis in the Grubbs group.


Increased efficiency in cross-metathesis reactions of sterically hindered olefins.
Stewart IC, et al.
Organic Letters, 10(3), 441-444 (2008)
Schrodi, Y.; Pederson, R.L.
Aldrichimica Acta, 40, 45-45 (2007)



Numéro d'article de commerce international

RéférenceGTIN
729345-100MG04061833555507
729345-2G04061832863023