Skip to Content
MilliporeSigma

Key Documents

View All Documentation

911607

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6

≥95%, powder or crystals

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):
C36H22F16IrN4O2P
CAS Number:
2307271-69-6
Molecular Weight:
1069.75
MDL number:
MFCD32672288
UNSPSC Code:
12161600
NACRES:
NA.22
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 , ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

mp

>300 °C

photocatalyst activation

465 nm

SMILES string

[Ir+](c5c(c(cc(c5)F)F)c6ncc(cc6)OC)c3c(c(cc(c3)F)F)c4ncc(cc4)OC.FC(F)(F)c1cnc(cc1)c2ncc(cc2)C(F)(F)F.F[P-](F)(F)(F)(F)F

InChI

1S/C12H6F6N2.2C12H8F2NO.F6P.Ir/c13-11(14,15)7-1-3-9(19-5-7)10-4-2-8(6-20-10)12(16,17)18;2*1-16-9-3-5-12(15-7-9)10-4-2-8(13)6-11(10)14;1-7(2,3,4,5)6;/h1-6H;2*2-3,5-7H,1H3;;/q;;;-1;+1

InChI key

VCHHFLJLUYSBMX-UHFFFAOYSA-N

Application

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the trifluoromethylation of alkyl bromides.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Copper-Catalyzed Trifluoromethylation of Alkyl Bromides

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Related Content

La boîte à outils de la réaction organique

Une boîte à outils de la réaction organique fournit des relations structure-activité permettant des réactions chimiques uniques afin de concevoir et de contrôler de façon optimale la synthèse de petites molécules.

David J P Kornfilt et al.
Journal of the American Chemical Society, 141(17), 6853-6858 (2019-04-16)
Copper oxidative addition into organohalides is a challenging two-electron process. In contrast, formal oxidative addition of copper to Csp2 carbon-bromine bonds can be accomplished by employing latent silyl radicals under photoredox conditions. This novel paradigm for copper oxidative addition has

Global Trade Item Number

SKUGTIN
911607-500MG04061841236719