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908568

[Ir(dFCF₃ppy)₂-(5,5’-dCF₃bpy)]PF₆

Name: [Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6
Brand: ALDRICH

≥95%, powder or crystals

Synonym(s):

[5,5′-Bis(trifluoromethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate

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About This Item

Empirical Formula (Hill Notation):

C₃₆H₁₆F₂₂IrN₄P

CAS Number:

1973375-72-2

Molecular Weight:

1145.69

MDL number:

MFCD31707657

UNSPSC Code:

12352101

NACRES:

NA.22

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Properties

Product Name

[Ir(dFCF₃ppy)₂-(5,5′-dCF₃bpy)]PF₆, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

mp

>300 °C

photocatalyst activation

460 nm

SMILES string

[Ir+](c5c(c(cc(c5)F)F)c6ncc(cc6)C(F)(F)F)c3c(c(cc(c3)F)F)c4ncc(cc4)C(F)(F)F.FC(F)(F)c1cnc(cc1)c2ncc(cc2)C(F)(F)F.F[P-](F)(F)(F)(F)F

InChI

1S/C12H6F6N2.2C12H5F5N.F6P.Ir/c13-11(14,15)7-1-3-9(19-5-7)10-4-2-8(6-20-10)12(16,17)18;2*13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-7(2,3,4,5)6;/h1-6H;2*1-2,4-6H;;/q;;;-1;+1

InChI key

QEXYETWHTSSWGM-UHFFFAOYSA-N

Description

Application

[Ir(dFCF₃ppy)₂-(5,5′-dCF₃bpy)]PF₆ is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations including the alkylation of remote C-H bonds and alkene aminoarylation.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer

Arylsulfonylacetamides as bifunctional reagents for alkene aminoarylation

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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