761435
cataCXium® A Pd G3
95%, solid
Synonym(s):
Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3
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About This Item
Product Name
cataCXium® A Pd G3, 95%
Quality Level
product line
Buchwald precatalyst Generation 3
assay
95%
form
solid
feature
generation 3
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
greener alternative product score
old score: 16
new score: 2
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impurities
≤3% acetone
mp
196-241 °C (decomposition)
functional group
phosphine
greener alternative category
SMILES string
CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7
InChI
1S/C24H39P.C12H10N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;
InChI key
REYVZCOGMIXVNX-DVBMAMJVSA-M
General description
Application
- Direct ortho-arylation of pyridinecarboxylic acids.
- Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
- Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
- Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.
- Boroperfluoroalkylation of terminal alkynes.
- Copper-free Sonogashira coupling reaction of aromatic halides with alkynes to form C-C bond.
- Suzuki cross-coupling between organotrifluoroborate and aryl halides.
Legal Information
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.
Tools aid in kit setup for organic chemistry techniques, ensuring ease and success.
All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form.
Related Content
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 761435-1G | 04061826251935 |
| 761435-25G | 04065271045330 |
| 761435-250MG | 04061832970622 |
| 761435-5G | 04061832970639 |