V800128
Copper(II) acetate
LR, ≥98%
Synonym(s):
Cupric acetate
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About This Item
Linear Formula:
Cu(CO2CH3)2
CAS Number:
Molecular Weight:
181.63
Beilstein:
3595638
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
Assay:
≥98%
Grade:
LR
Form:
powder
grade
LR
vapor density
6.9 (vs air)
product line
Vetec™
Assay
≥98%
form
powder
pH
5.2-5.5 (20 °C, 20 g/L)
SMILES string
CC(=O)O[Cu]OC(C)=O
InChI
1S/2C2H4O2.Cu/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
InChI key
OPQARKPSCNTWTJ-UHFFFAOYSA-L
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Legal Information
Vetec is a trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Skin Corr. 1B
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
does not flash
Flash Point(C)
does not flash
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Cinthia da S Lisboa et al.
The Journal of organic chemistry, 76(13), 5264-5273 (2011-05-25)
The oxidative addition of anilines (2) with 1,4-naphthoquinone (3) to give N-aryl-2-amino-1,4-naphthoquinones (1) was found to be catalyzed by copper(II) acetate. In the absence of the catalyst, the reactions are slower and give lower yields with the formation of many
Hanmei Zheng et al.
The Journal of organic chemistry, 74(2), 943-945 (2008-12-11)
A novel copper-catalyzed protocol for the synthesis of carbinol derivatives has been developed. In the presence of copper(II) acetate and dppf, carbinol derivatives were prepared by the addition of arylboronic acids to aromatic aldehydes in good to excellent yields. Moreover
Catherine Bronner et al.
Inorganic chemistry, 49(19), 8659-8661 (2010-09-02)
Reaction of a heteroleptic cyclometalated iridium complex incorporating a carboxylic acid appended dipyrrin with copper acetate leads to the formation of a hexanuclear species with the paddlewheel structure.
Jaesook Yun et al.
Chemical communications (Cambridge, England), (41)(41), 5181-5183 (2005-10-18)
A new, air stable and well-defined carbene-copper(II) complex has been prepared, which is an efficient precatalyst for the 1,2- and 1,4-reduction of carbonyl compounds under hydrosilylation conditions.
Liang Li et al.
Organic letters, 14(13), 3506-3509 (2012-06-26)
New strategies for the oxidative cycloaddition of enones with enamines are developed. These cycloaddition reactions directly afford substituted aromatic amines, which are important in organic chemistry, in moderate to good yield. Cu(OAc)(2)/TFA is shown to be essential to achieve high
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